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World of Carbon

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One method of natural synthesis is retrosynthetic research. With this process a chemist will begin with the constitution in their objective molecule and steadily minimize bonds to create less complicated molecules. Reversing this technique offers a man-made path to the objective molecule from easier beginning fabrics.

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Evans DA, Takacs JM, McGee LR, Ennis MD, Mathre DJ, Bartroli J (1981) Pure Appl Chem 53:1109 35. Evans DA (1982) Aldrichimica Acta 15:23 36. Braun M (1981) Angew Chem Int Ed Engl 26:24 37. Inoue T, Liu JF, Buske DC, Abiko A (2002) J Org Chem 67:5250 38. Fanjul S, Hulme AN, White JW (2006) Org Lett 8:4219 39. Evans DA, Sjorgren EB, Bartroli J, Dow RL (1986) Tetrahedron Lett 27:4957 40. Evans DA, Dow RL, Shih TL, Takacs JM, Zahler R (1990) J Am Chem Soc 112:5290 41. Evans DA, Weber AE (1986) J Am Chem Soc 108:6557 42.

Evans DA, Cee V, Siska SJ (2006) J Am Chem Soc 128:9433 46. (a) Goodman JM, Paton RS (2007) Chem Commun 2124; (b) Paton RS, Goodman JM (2008) J Org Chem 73:1253; (c) Paton, RS, Goodman JM (2006) Org Lett 8:4299 38 2 Aldol Reactions with Preformed Enolates 47. (a) Dias LC, Aguilar AM (2006) Org Lett 8:4629; (b) Dias LC, De Marchi AA, Ferreira MAB, Aguilar AM (2007) Org Lett 9:4869; (c) Dias LC, Aguilar AM (2008) Chem Soc Rev 37:451 48. Mori Y, Kobayashi J, Manabe K, Kobayashi S (2002) Tetrahedron 58:8263 49.

59 Elaiolide belongs to the efomycines – a class of anti-inflammatory agents isolated from microorganisms. 14). 10 Boron enolate aldol additions in total synthesis of spongistatin An efficient synthesis of epothilone D analogs has been developed using highly stereoselective boron enolate aldol addition. 61 During the total synthesis of australine a defined configured stereopentad was required. r. r. 63 The α-oxygen-containing aldehyde 71 was deployed in a convergent total synthesis of pteridic acid A.

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